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oscillations

(10 points)5. Series 36. Year - S. ethanol or methanol?

The binding energy of a fluorine molecule is approximately $37 \mathrm{kcal/mol}$. Assuming the range of binding interactions to be approximately $3 \mathrm{\AA }$ from the optimum distance, what (average) force do we have to exert to break the molecule? Calculate the „stiffness“ of the fluorine molecule if such an average force was applied in the middle of this range. What would be the vibrational frequency of this molecule? Compare this with the experimental value of $916{,}6 \mathrm{cm^{-1}}$. ($4 \mathrm{pts}$)

Using Psi4, calculate the dissociation curve $\mathrm {F_2}$ and fit a parabola around the minimum. What value will you get for the energy of the vibrational transitions this time? ($3 \mathrm{pts}$)

You are given two bottles of alcohol that you found suspicious, to say the least. After taking them to the lab, you obtain the following Raman spectra from them. Using the Psi4 program, calculate the frequencies at which the vibrational transitions of both the methanol and ethanol molecules occur. Use this to determine which bottle contains methanol and which one contains ethanol. You can use the approximate geometries of ethanol and methanol, which are included in the problem statement on the web. ($3 \mathrm{pts}$)

Raman spectra of bottle A Raman spectra of bottle B

(10 points)3. Series 36. Year - 5. guitar

Assume you have a guitar that is perfectly tuned at room temperature. By how many semitones (in tempered tuning) will the individual strings be out of tune if we move to a campfire, where it is cooler by $10 \mathrm{\C }$? Will the guitar still sound in tune? The distance between the string attachment points is $d = 65 \mathrm{cm}$. The strings have a density $\rho = 8~900 \mathrm{kg.m^{-3}}$, a Young's modulus of elasticity $E = 210 \mathrm{GPa}$ and a thermal expansion coefficient $\alpha = 17 \cdot 10^{-6} \mathrm{K^{-1}}$.

Honza's guitar is out of tune again.

(3 points)1. Series 36. Year - 1. useful butter

Jarda decided to bake a cake but he found out that the battery in his kitchen scale was dead, so he can't weigh $300 \mathrm{g}$ of flour. However, he had the idea that he could use a block of butter instead. The packaging said its weight is $m = 250 \mathrm{g}$. Fortunately, he found a suitable spring and a stopwatch. He put a heap of flour in a very light bowl, attached it to the spring, perturbed it and measured the period of oscillations $T_1=2,8 \mathrm{s}$. He repeated the same process with the cube of butter and measured $T_2 = 2,3 \mathrm{s}$. How much flour does Jarda need to add or remove?

When Jarda gets kicked out of Matfyz, he will open a bakery.

(8 points)1. Series 36. Year - 5. U-tube again

We have a U-tube with length $l$ and cross-sectional area $S$. We pour volume $V$ of water into the tube. The volume $V$ is large enough that the whole U-turn is filled with water but $Sl > V$. When water levels in both arms of the tube are at rest, we seal one of the arms. What is the period of small oscillations of water in the tube?

Karel went crazy again.

(5 points)4. Series 35. Year - 3. pendular collisions

Two small marbles are attached to ends of strings of the same length ($l = 42,0 \mathrm{cm}$) and negligible mass. The other ends of both strings are attached to a single point. The marbles are of the same size, but they are made from the different materials. First one is made of steel ($\rho _1 = 7~840 kg.m^{-3}$) and second one is made of dural ($\rho _2 = 2~800 kg.m^{-3}$). Both marbles are initially at the angle $5\dg $ with respect to the equilibrium position, and after releasing them, they collide elastically. What is the maximum height the individual marbles reach after the collision? What is the result after the second collision?

Karel wanted to hypnotize others. You want to solve this problem \dots

(7 points)4. Series 35. Year - 4. Analogy

Assume we have two linear springs with elastic modulus $E = 2{,}01 \mathrm{GPa}$ and a piston with viscosity $\eta = 9,8 \mathrm{GPa\cdot s}$. The dependence of stress $\sigma $ on relative extension $\epsilon $ is characterized by formula $\sigma \_s = E\epsilon \_s$ for spring, and by formula $\sigma \_d = \eta \dot {\epsilon }\_d$ for piston, where the dot represents the time derivative (Newton's notation). We connect a spring of length $l\_s$ and a piston of length $l\_d$ into series, and then we connect the other spring of length $l\_p$ in parallel to them. Abruptly, we stretch the entire system into the state of $\epsilon _0 = 0{,}2$, and we hold the extension constant. Determine, in what time (from stretching) will the stress decrease to half of the original value, if $\frac {l\_s}{l\_p} = 0{,}5$ holds.

Mirek was thinking about problems while taking an exam.

(9 points)6. Series 34. Year - 5. heavy spring

Let us have a homogeneous spring with stiffness $k$, mass $m$ and its width negligible compared to its length. We grip the spring at one end in a way that it can rotate around and then we spin it with angular velocity $\omega $. By how much does the spring prolong (compared to its initial length) due to the rotation? Neglect the effect of the gravitational field.

Jachym had a very difficult day and wanted to share it with others.

(10 points)6. Series 34. Year - S. charged chord

Assume a charged chord with linear density $\rho $, uniformly charged with linear charge density $\lambda $. The tension in the chord is $T$. It is placed in a magnetic field of constant magnitude $B$ pointing in the direction of the chord in equilibrium. Your task is to describe several aspects of the chord's oscillations. First, we want to write the appropriate wave equation. Neglect the effects of electromagnetic induction (assume the chord to be a perfect insulator; that also means the charge density does not change) and find the Lorentz force acting on an unit length of the chord for small oscilations in both directions perpendicular to the equilibrium position. Use this force to write the wave equation (which will also include the effects of the tension). Apply the Fourier substitution and determine the disperse relation in the approximation of a weak field $B$; more specifically, neglect the terms that are of higher than linear order in $\beta = \frac {\lambda B}{k \sqrt {\rho T}} \ll 1$, where $k$ is the wavenumber. Find two polarization vectors, this time neglect even the linear order of $\beta $. Now suppose that in a particular spot on the chord, we create a wave oscilating only in one specific direction. How far from the original spot will be the wave rotated by ninety degrees from the original direction?

Štěpán was nostalgically remembering the third serial task.

(10 points)4. Series 34. Year - S. Oscillations of carbon dioxide

We will model the oscillations in the molecule of carbon dioxide. Carbon dioxide is a linear molecule, where carbon is placed in between the two oxygen atoms, with all three atoms lying on the same line. We will only consider oscillations along this line. Assume that the small displacements can be modelled by two springs, both with the spring constant $k$, each connecting the carbon atom to one of the oxygen atoms. Let mass of the carbon atom be $M$, and mass of the oxygen atom $m$.

Construct the set of equations describing the forces acting on the atoms for small displacements along the axis of the molecule. The molecule is symmetric under the exchange of certain atoms. Express this symmetry as a matrix acting on a vector of displacements, which you also need to define. Furthermore, determine the eigenvectors and eigenvalues of this symmetry matrix. The symmetry of the molecule is not complete – explain which degrees of freedom are not taken into account in this symmetry.

Continue by constructing a matrix equation describing the oscillations of the system. By introduction of the eigenvectors of the symmetry matrix, which are extended so that they include the degrees of freedom not constrained by the symmetry, determine the normal modes of the system. Determine frequency of these normal modes and sketch the directions of motion. What other modes could be present (still only consider motion along the axis of the molecule)? If there are any other modes you can think of, determine their frequency and direction.

Štěpán was thinking about molecules

(10 points)3. Series 34. Year - S. electron in field

Consider a particle with charge $q$ and mass $m$, fixed to a spring with spring constant $k$. The other end of the spring is fixed at a single point. Assume that the particle only moves in a single plane. The whole system exists in a magnetic field of magnitude $B_0$, which is perpendicular to the plane of movement of the particle. We will try to describe possible modes of oscillation of the particle. Start by the determination of equations of motion – do not forget to include the influence of the magnetic field.

Next assume that the particle oscillates in both of the cartesian coordinates of the particle and carry out Fourier substitution – substitute derivatives by factors of $i \omega $, where $\omega $ is the frequency of the oscillations. Solve the resultant set of equations in order to determine the ration of the amplitudes of oscillations in both coordinates and the frequency of oscillations. The solution obtained in this way is quite complicated, and better physical insight can be gained in a simpler case. From now on, assume that the magnetic field is very strong, i.e. $\frac {q^2 B_0^2}{m^2} \gg \frac {k}{m}$. Determine the approximate value(s) of $\omega $ in this case, always up to the first non-zero order. Next, sketch the motion of the particle in the direct (i.e. real) space in this (strong field) case.

Štěpán wanted to create a classical diamagnet.

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